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Cerium(IV) Oxide (CeO₂)  High-Performance Rare Earth Oxide

Cerium(IV) Oxide, also called ceric oxide or simply cerium dioxide, is a pale yellow-white rare earth oxide with a wide range of industrial, chemical, and polishing applications.

🧾 Basic Information:

  • Chemical Formula: CeO₂
  • Oxidation State of Cerium: +4
  • Molar Mass: 172.11 g/mol
  • Appearance: Pale yellow-white fine powder
  • Melting Point: ~2,400 °C
  • Insoluble in water; soluble in acids

⚙️ Main Applications:

Glass and Optical Polishing

  • Most popular use: ultra-fine abrasive for glass, mirrors, camera lenses, and windshields
  • Replaces traditional polishing agents like iron oxide

Catalysis

  • Used in automotive catalytic converters to reduce NOₓ and CO emissions
  • Acts as an oxygen buffer due to its redox property (Ce⁴⁺ ↔ Ce³⁺)

Fuel Cells and Electronics

  • Used in solid oxide fuel cells (SOFCs) as an electrolyte or electrode component
  • Employed in semiconductors, solar cells, and as a dielectric in electronics

UV Absorption and Coatings

  • Added to UV-resistant coatings and ceramics
  • Sometimes used in sunscreen formulations (as nano-CeO₂)

🧪 Chemical Properties:

  • Strong oxidizing agent in acidic conditions
  • Under reducing environments, CeO₂ can be partially reduced to Ce₂O₃
  • High oxygen storage capacity (OSC), useful in dynamic catalytic systems

⚠️ Safety & Handling:

  • Generally low toxicity but inhalation of fine dust should be avoided
  • Use standard PPE: gloves, goggles, dust mask when handling powder
  • Store in a cool, dry, and ventilated area